tert-butylmagnesium chloride（CAS# 677-22-5)
| Nā Code Risk | R12 – Pahu loa R14/15 - R19 - Hiki ke hana i nā peroxide pahū R22 – Poino ke aleia R34 - Ke kumu o ke kuni R66 – Hiki ke hoʻomaloʻo a pohā paha ka ʻili i ka hoʻolaha pinepine ʻia R67 – Hiki i ka mahu ke kumu i ka hiamoe a me ka poni R15 – Hoʻokuʻu ʻia ka pilina me ka wai i nā kinoea wela loa R11 – Hiki ke ahi R14 – Hana ikaika me ka wai R37 - Hoʻonāukiuki i ka ʻōnaehana hanu R17 – Paa wale i ka ea R40 - Nā hōʻike liʻiliʻi o ka hopena carcinogenic |
| Ka wehewehe palekana | S9 - E mālama i ka pahu ma kahi e hoʻoheheʻe maikaʻi ʻia. S16 – E hoʻokaʻawale i nā kumu hoʻā. S26 – Inā pili me nā maka, e holoi koke me ka wai nui a e ʻimi i ka ʻōlelo aʻo kino. S29 – Mai hoʻokahe i loko o nā kahawai. S33 - E mālama i nā hana e pale aku ai i ka hoʻokuʻu ʻana. S36/37/39 – E hoʻohana i nā lole pale kūpono, nā mīkina lima a me ka pale maka/maka. S43 – Inā hoʻohana ʻia ke ahi… (ma hope o ke ʻano o nā lako hana ahi e hoʻohana ʻia.) S45 – Inā loaʻa ka pōʻino a i ʻole ka maikaʻi ʻole, e ʻimi koke i ka ʻōlelo aʻo kino (e hōʻike i ka lepili inā hiki.) |
| UN ID | UN 3399 4.3/PG 1 |
| WGK Kelemānia | 1 |
| NUI FLUKA BRAND F | 1-3-10 |
| HS Code | 29319090 |
| Papa Hazard | 4.3 |
| Hui Pūʻulu | I |
Hoʻolauna
helu hehee -108 ℃ (Tetrahydrofuran)
0.931g/mL ma 25 c
Ke kiko uila 34 °F
Nā kūlana mālama 2-8°C
ʻO ke kinowai wai
kala ʻeleʻele ʻeleʻele a ʻeleʻele
Hiki ke hoʻoheheʻe ʻia me ka wai ʻona a me ka wai.
Nani ka ea a me ka nawaliwali
BRN 3535403
InChIKey ZDRJSYVHDMFHSC-UHFFFAOYSA-M
Hoʻomākaukau
Ka hoʻomākaukau ʻana i ka tert-butyl magnesium chloride: E hoʻohana i ke one no ka wehe ʻana i ke kiʻi oxide ma ka ʻili o ka ʻili magnesium a ʻokiʻoki i loko o nā ʻāpana liʻiliʻi. ʻO 3.6g(0.15 mol) o ka magnesium chips, i hoʻohui ʻia i ka pahu ʻāʻī ʻehā i hoʻolako ʻia me kahi mea pale nitrogen, kahi mea hoʻouluulu, kahi reflux condenser a me kahi pahu hoʻoheheʻe kaomi mau (ua kau ʻia ka pahu maloʻo CaCl2 ma luna o ka condenser reflux. paipu), hoʻokomo i ka naikokene i loko o ka ʻōmole hopena no kahi o 10 min, wehe i ka ea i loko o ka ipu ʻāʻī ʻehā, a laila hoʻoponopono i ka kahe kahe o ka nitrogen, a hoʻomau. hoʻokomo ʻia ka naikokene liʻiliʻi loa i loko o ka ʻōnaehana pane. Hoʻohui ʻia he 35 mL o ka tetrahydrofuran i hoʻomaʻemaʻe ʻia i loko o ka hue ʻāʻī ʻehā, a laila kaupaona ʻia 13.9g(0.15 mol) o tert-butyl chloride, ma kahi o 3.5g o tert-butyl chloride e hoʻohui ʻia i ka hue ʻāʻī ʻehā ma mua, a ʻo ke koena. Hoʻohui ʻia ka 10.4g tert-butyl chloride me 150 mL o ka mea hoʻomaʻemaʻe. tetrahydrofuran a laila hoʻohui ʻia i kahi funnel hoʻokaʻawale kaomi mau. E hoʻohui i kahi hua liʻiliʻi o ka iodine, wela iki, hoʻoulu ʻia kahi liʻiliʻi o nā ʻōpū, emi ke kala o ka iodine, ʻoi aku ka maikaʻi o ka mālama ʻana i ka ʻōnaehana hopena ma hope o ka hoʻomaka ʻana o ka hopena, ma hope o ka hāʻule ʻana, e hoʻāla no 3-4 mau hola, a hiki i ka nalo ʻana o nā ʻāpana magnesium, e hōʻike ana i kahi hopena hina.
ʻike palekana
Hōʻailona nā waiwai pōʻino f, c, f
Helu helu pōʻino 12-14/15-19-22-34-66-67-15-11-14-37-17-40
Nā kuhikuhi palekana 9-16-26-29-33-36/37/39-43-45
Helu lawe waiwai ʻino UN 3399 4.3/PG 1
WGK Kelemānia 1
F 1-3-10
HazardClass 4.3
ʻO ka Hui Pūʻulu I
Helu 29319090
