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Triphenylphosphine(CAS#603-35-0)

Waiwai Kemika:

ʻĀpana Molekala C18H15P
Molar Mass 262.29
ʻO ka mānoanoa 1.132
Lae hehee 79-81°C(māmā)
Lae Boling 377°C(māmā)
Lae Flash 181 °C
Hiki i ka wai ʻAʻole hiki ke hoʻoheheʻe
Ka hikiwawe wai: hoʻoheheʻe 0.00017 g/L ma 22°C
Puʻupuʻu mahu 5 mm Hg (20 °C)
Ka māhu māhu 9 (vs ea)
Ka nana aku Nā Kilika, ʻO ka pauka Crystalline a i ʻole nā ​​Flakes
Kaumaha Kūikawā 1.132
kalakala Keʻokeʻo
ʻO Merck 14,9743
BRN 610776
Kūlana Waihona E mālama ʻia ma lalo o +30 ° C.
Paʻa Paʻa. ʻAʻole kūpono me nā mea oxidizing, nā waikawa.
Pilikino 8: hana wikiwiki me ka makū, ka wai, nā mea hoʻoheheʻe protic
Hōʻike Hōʻike 1.6358
Na Waiwai Kino a Kimia ʻO ka mānoanoa 1.132
helu hehee 78.5-81.5°C
wahi hoʻolapalapa 377°C
kiko uila 181°C
wai-soluble insoluble
Hoʻohana Hoʻohana ʻia i ka synthesis organik, hoʻohana ʻia e like me ka polymerization initiator, antibiotic drug clindamycin a me nā mea ʻē aʻe.

Huahana Huahana

Huahana Huahana

Nā Code Risk R22 – Poino ke aleia
R43 – Hiki ke hoʻonāwaliwali i ka ʻili
R53 – Hiki ke hoʻoulu i nā hopena pōʻino no ka wā lōʻihi ma ke kaiaola wai
R50/53 – He mea ʻawaʻawa loa i nā mea ola i loko o ka wai, hiki ke hoʻopōʻino i ka wā lōʻihi i ke kaiaola.
R48/20/22 -
Ka wehewehe palekana S36/37 – E hoʻohana i nā lole pale kūpono a me nā mīkina lima.
S60 - Pono e hoʻolei ʻia kēia mea a me kāna pahu ma ke ʻano he ʻōpala weliweli.
S61 - Hōʻalo i ka hoʻokuʻu ʻana i ke kaiapuni. E nānā i nā ʻōlelo kuhikuhi kūikawā / pepa ʻikepili palekana.
S36/37/39 – E hoʻohana i nā lole pale kūpono, nā mīkina lima a me ka pale maka/maka.
S26 – Inā pili me nā maka, e holoi koke me ka wai nui a e ʻimi i ka ʻōlelo aʻo kino.
UN ID 3077
WGK Kelemānia 2
RTECS SZ3500000
NUI FLUKA BRAND F 9
TSCA ʻAe
HS Code 29310095
Kaʻawaʻawa LD50 ma ka waha i loko o ka Lapeti: 700 mg/kg LD50 dermal Rabbit > 4000 mg/kg

 

Hoʻolauna

ʻO Triphenylphosphine kahi hui organophosphorus. ʻO kēia ka hoʻolauna ʻana i nā waiwai, hoʻohana, nā ʻano hoʻomākaukau a me ka ʻike palekana o ka triphenylphosphine:

 

ʻAno maikaʻi:

1. Nānā: Triphenylphosphine he keʻokeʻo i ka melemele crystalline a i ʻole ka pauka paʻa.

2. Solubility: He mea hiki ke hoʻoheheʻe maikaʻi ʻia i nā solvents non-polar e like me benzene a me ka etera, akā hiki ʻole ke hoʻoheheʻe ʻia i ka wai.

3. Paʻa: ʻO Triphenylphosphine kahi paʻa i ka lumi wela, akā e hoʻoheheʻe ʻia ma lalo o ka mana o ka oxygen a me ka wai i ka lewa.

 

E hoʻohana:

1. Ligand: ʻO Triphenylphosphine kahi ligand koʻikoʻi i ka kemika hoʻohui. Hoʻokumu ia i nā paʻakikī me nā metala a hoʻohana nui ʻia i ka synthesis organik a me nā hopena catalytic.

2. Mea ho'ēmi: Hiki ke hoʻohanaʻia ka Triphenylphosphine ma keʻano he mea hoʻohaʻahaʻa maikaʻi no ka ho'ēmiʻana i nā pūhui carbonyl i nāʻano likeʻole.

3. Nā mea hoʻoheheʻe: Hoʻohana pinepine ʻia ka Triphenylphosphine a me kāna mau mea e like me nā ligands no nā catalysts metal transition a komo i nā hopena synthesis organik.

 

Hanana:

Hoʻomākaukau mau ʻia ka triphenylphosphine e ka hopena o ka triphenylphosphonyl hydrogenated a i ʻole triphenylphosphine chloride me ka metala sodium (a i ʻole lithium).

 

ʻIke palekana: Pono e ʻaʻahu ʻia nā lako pale pilikino e like me nā mīkina lima a me nā maka.

2. E pale aku i ka hoopili ana me na mea oxidants a me na waika ikaika, i mea e hooulu ai i na hopena pilikia.

3. Pono e mālama ʻia ma kahi maloʻo a me ka makani, kahi mamao mai nā mea like ʻole a me nā kumu ahi.

 


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